alkene

Alkene

Reactions

Dehydrohalogenation of haloalkane

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Haloalkane added with ethanolic \[\ce{NaOH}\] (\[\ce{NaOH}\] dissolved in ethanol) when heated produces alkene.

Dehydration of alcohol

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The reagents to this reaction is either concentrated acid such as \[\ce{H2SO4}\] or a heated catalyst such as \[\ce{Al2O3}\].

Oxidation of alkene with hot concentrated acidified \[\ce{KMnO4}\]

The acidified \[\ce{KMnO4}\] solution oxidizes the alkene by breaking the carbon-carbon double bond and replacing it with two carbon-oxygen double bonds.
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The products are known as carbonyl compounds because they contain the carbonyl group, \[\ce{C=O}\].

Now, here's where the reaction branches out.

  • Both attached \[\ce{R}\] groups are alkyl (\[\ce{-CH3}\]) groups

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    These carbonyl compounds are now identified as ketones. Ketones aren't that easy to oxidize, and so there is no further action. Though is a gross over-simplification. In practice, ketones are also oxidized by \[\ce{KMnO4}\] under these conditions. The reaction is untidy and results in breaking carbon-carbon bonds either side of the carbonyl group. This is because \[\ce{KMnO4}\] is a devastating oxidizing agent, which is also why it is rarely used in organic chemistry reactions.

  • One hydrocarbon group and one hydrogen

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    In this case, the products we get are an aldehyde and a ketone. As mentioned above, it's simpler to assume ketone doesn't oxidise anymore. However, aldehydes do oxidize further to give carboxylic acid.
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  • Two hydrogens, but no hydrocarbon group

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    However, since methanoic acid is also easily oxidised by \[\ce{KMnO4}\], it will further get oxidised into carbon dioxide and water:
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Electrophilic addition of hydrogen halides to alkene

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\[\ce{\text{alkene} + HX ->[][\text{room temp.}] \text{halogenoalkane}}\]. This reaction follows Markovnikov's rule.

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Electrophilic addition of halogens to alkene

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\[\ce{R2C=CR2 + X2 -> R2CX-CR2X}\].

Addition polymerization of alkenes

Ethene is known as the monomer, while polythene is the polymer:
\[\ce{nCH2=CH2 -> [-CH2-CH2-]_{n}}\].

An addition reaction is one in which two or more molecules join together to give a single product. During the polymerisation of ethene, thousands of ethene molecules join together to make poly(ethene) - commonly called polythene.

Or, in the case of propene:
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